substituent In A Sentence
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- However, when the organic substituent is very large, the diphosphene becomes stable.
- Kinetic and thermodynamic stabilization will be provided via extensive spin delocalization and substituent electronic effects.
- The methyl " substituent " or " group " is highlighted red.
- If you like indanone as the parent structure, then the substituent is a benzylidine derivative.
- In the " ? anomer ", the-OH substituent on the anomeric carbon rests on the opposite side ( trans ) of the ring from the CH 2 OH side branch.
- If the O-glycosidic bond to the anomeric carbon ( C 1 ) was in the same plane as the substituent, it would be classified as a ? ( 1 ?. 4 ) bond, and the resulting molecule would be cellobiose.
- A methyl ester substituent was reported in 1958.
- These results indicated that a suitable substituent at the 2-position of pyridine ring and a well-fit group at the 3-position of acrylate were both essential for hi.
- The polar effect exerted by a substituent is a combination of the inductive effect and the mesomeric effect.
- In fact, the sign of the charge and degree to which it develops will be affected by the substituent in the case of the benzylic system.
- This is because in the cyclohexane ring, Y = carbon, which is not a heteroatom, so the anomeric effect is not observed and sterics dominates the observed substituent position.
- Thus, the resultant Yukawa-Tsuno effective substituent constant is given by:.
- If the substituent groups are different, then the molecule will be chiral.
- By contrast, the exo adduct possesses a trans relationship between the dienophile electron-withdrawing group and the trans diene substituent .
- For reactive dyes, there is no revolution in chromophore parent and reactive group, the focuses are on the substituent group to improve the dyeing behaviors and commercialized technology.
- The non-fluorine substituent is not capable of doing so.
- The reaction appears to be perfectly general unless the ketone contains two ortho-substituent groups.
- Reaction with dimethylamine affords the [ 2.2 . 2 ] propellane backbone with a dimethylamide substituent "'10 " '.
- In "'hemi isotactic macromolecules "'every other repeat unit has a random substituent.
- The clearest experimental evidence against electrostatic substituent effects was reported by Rashkin and Waters.
- RTI-31 can easily be " cleaned " though, as is done, for instance, by replacing the carbomethoxy ester with a more sterically occluded substituent such as is done for RTI-113.
- It is a derivative of pyridine with a carboxylic acid substituent at the 4-position.
- A suitable substituent in the adjacent meta position should avoid this clash and permit an additional interaction with the enzyme (J.H.
- Again, the substituent groups are ordered alphabetically.
- The fluorescence intensity of porphyrin also relates to the substituent positions on the phenyl groups.
- The 1,3,2,4-dithiadiazoles show a 1:1:1 triplet due to the spare electron being largely localised at the nitrogen atom remote from the ring substituent.
- A substituent with ?-bonding ability also prefers equatorial positions.
- An "'allyl "'group is a substituent with the structural formula H 2 C = CH-CH 2 R, where R is the rest of the molecule.
- Those compounds with the 4-propionoxy substituent appear to be the most potent analgesics.
- Glaxo refined the model further by replacing the imidazole-ring of cimetidine with a furan-ring with a nitrogen-containing substituent, and in doing so developed ranitidine.
- This is a great substituent for soy sauce.
- When this center is an electron rich carbanion or an alkoxide anion, the presence of the electron-withdrawing substituent has a stabilizing effect.
- Other investigators have thought the protonation is meta ( 1, 3 ) to the substituent.
- Independent of the substituent, they all exhibit an para directing effect.
- IAA is a derivative of indole, containing a carboxymethyl substituent.
- The tacticity of polymers is mainly influenced by the polarity of substituent group of vinyl monomer.
- Orientation of substituent Groups.-The determination of the relative positions of the substituents in a benzene derivative constitutes an important factor in the general investigation of such compound
- In general, cyanide is an electronegative substituent.
- These clusters show different fluxional behaviour and ligands according to various substituent around the metals of osmium.
- This is most likely due to the bulky bromine substituent on the side chain.
- Formylation occurs ortho to the electron donating substituent preferentially, unless the ortho positions are blocked, in which case the formylation occurs para.
- Other substituents, like methoxy and ethoxy, can even have opposite signs for the substituent constant as a result of opposing inductive and mesomeric effect.
- The net electron flow from or to the substituent is determined also by the inductive effect.
- When the substituent at the benzene ring and the N atom of aniline, the HDAC inhibition activity is different from that of SAHA.
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