claisen In A Sentence
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- One experiment that it is used for is the claisen rearrangement.
- Claisen, whose views are now accepted, studied the reactions of sodium ethylate and showed that if sodium ethylate be used in place of sodium in the above reaction the same result is obtained.
- Crossed claisen condensations, in which the enolate and nucleophile are different esters, are also possible.
- Allyl - cyclohexenyl zinc undergoes the metalla - claisen rearrangement leading to 2 - allyl 1, 1 -Gemdimetallic - cyclohexane.
- Interestingly, they used a claisen condensation reaction to construct the C ( 13 ) -C ( 14 ) trisubstituted Z-olefin.
- Sodium ethoxide is commonly used in the claisen condensation and malonic ester synthesis.
- The key steps were the iodization rearrangement of 2,3 epoxy alcohol 6 and claisen rearrangement of allyl vinyl ether 8.
- Overman is most known for the Overman rearrangement, a claisen rearrangement of allylic alcohols to give allylic trichloroacetamides.
- The thiolase superfamily enzymes catalyse the carbon-carbon-bond formation via a thioester-dependent claisen condensation reaction mechanism.
- After the generation of a thioester-linked tetraketide, a regiospecific C1, C6 claisen condensation occurs, forming a new ring system to generate naringenin chalcone.
- Tandem Wittig-Claisen reaction has also been applied to the construction of the spiro [ pyrrolidin-3, 3'-oxindole ] ring system in natural products such as horsfiline.
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